Spherical tensors, in one paragraph

Jun 24, 2026

A rank-nn Cartesian tensor carries a reducible representation of the rotation group. Decomposing it into spherical tensors Tq(k)T^{(k)}_q block-diagonalizes the action of rotations: each irreducible piece transforms only among its own 2k+12k+1 components, via the Wigner-D matrices,

Tq(k)  ⟼  ∑q′Dq′q(k)(R) Tq′(k).T^{(k)}_q \;\longmapsto\; \sum_{q'} D^{(k)}_{q'q}(R)\, T^{(k)}_{q'} .

A point-group constraint then reduces to asking which components survive averaging over the group — which, in this basis, is almost by inspection.

For example, the second-harmonic susceptibility χijk(2)\chi^{(2)}_{ijk} — a rank-3 polar tensor — decomposes as 1⊗(1⊗1)sym1 \otimes (1 \otimes 1)_{\mathrm{sym}}, giving angular-momentum content k∈{1,2,3}k \in \{1, 2, 3\}. It is exactly this content that the calculator tabulates for any (magnetic) point group.

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